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東邦大学理学部
化学科
錯体化学教室

〒274-8510
千葉県船橋市三山2-2-1
習志野学事部入試広報課
TEL 047-472-0666

加知 千裕 教授

研究論文

  1. “Modification of proteins with azobenzene crosslinkers using reversible covalent bonds” Nobuo Yasuike, Chihiro Kachi-Terajima, Amir Karin, Takashi Mino, and G. Andrew Woolley*, Org. Biomol. Chem., 2022, 20, 8649–8656.
  2. “Synthesis, crystal structure and determination of the pKa value of 2,6-dimethoxycyclohexa-2,5-diene-1,4-dione 1-[2-(quinolin-8-yl)hydrazone]” Chihiro Kachi-Terajima,* Yuto Inaba, and Kaito Tsuruga, Acta Cryst., 2022, C78, 371–375.
  3. “Synthesis, crystal structure and photophysical properties of chlorido [(E)-3-hydroxy-2-methyl-6-(quinolin-8-yldiazenyl)phenolato]copper(II) monohydrate” Chihiro Kachi-Terajima* and Seiya Hagiwara, Acta Cryst., 2022, E78, 473–476.
  4. “Luminescence switch based on the acid/base induced reversibility of covalent bonds in lanthanide(III) complexes” Chihiro Kachi-Terajima,* Miku Okubo, Mari Ikeda, and Yoichi Habata, Chem. Commun., 2021, 57, 10939-10942.
  5. “Cyclometalation reactions of platinum complexes with azo- and imine-based ligands: Ligand-dependent and water-induced C–H activation” Chihiro Kachi-Terajima,* Naoya Mutoh, Yuta Sasada, and Kaori Anjo, J. Organomet. Chem., 2020, 928, 121548. Special issue of JOM for "stimuli-responsive organometallic complexes"
  6. “Spin Ice‐like Magnetic Relaxation of a Two‐dimensional Network based on Manganese(III) Salen‐type Single‐Molecule Magnets” Chihiro Kachi-Terajima,* Tasuku Eiba, Rikako Ishii, Hitoshi Miyasaka, Yuta Kodama, and Toshiaki Saito, Angew. Chem. Int. Ed., 2020, 59, 22048–22053, Hot Paper, Frontispiece
  7. “Solvent-dependent structures of lanthanide–TCNQ coordination networks and their magnetic properties”, Chihiro Kachi-Terajima,* Norihisa Kimura, Yuka Tomori, Daiisuke Akahoshi, Toshiaki Saito, J. Coord. Chem., 2018, 71, 3600–3614.
  8. “Crystal structures of two isotypic lanthanide(III) complexes: triaqua[2,6-diacetylpyridine bis(benzoylhydrazone)]methanollanthanide (III) trichloride methanol disolvates (LnIII = Tb and Dy)”, Chihiro Kachi-Terajima,* Norihisa Kimura, Acta Cryst., 2018, E74, 535–538.
  9. “A hemiaminal–ether structure stabilized by lanthanide complexes with an imidazole-based Schiff base ligand”, Chihiro Kachi-Terajima,* Takeru Shimoyama, Takahiro Ishigami, Mari Ikeda and Yoichi Habata, Dalton Trans., 2018, 47, 2638–2645.
  10. “Ferromagnetic Exchange Coupling in a Family of MnIII Salen-Type Schiff-Base Out-of-Plane Dimers”, Chihiro Kachi-Terajima,* Rikako Ishii, Yoshiaki Tojo, Masato Fukuda, Yasutaka Kitagawa, Mizuki Asaoka, and Hitoshi Miyasaka, J. Phys. Chem. C, 2017, 121, 12454−12468.
  11. “C–H⋯Cl− hydrogen bonds in solution and in the solid-state: HgCl2 complexes with cyclen-based cryptands”, Mari Ikeda, Ajay Kumar Sah, Miki Iwase, Rina Murashige, Jun-ichi Ishi-i, Masatoshi Hasegawa, Chihiro Kachi-Terajima, Ki-Min Park, Shunsuke Kuwahara and Yoichi Habata, Dalton Trans., 2017, 46, 3800–3804.
  12.  “Homochiral 1D Helical Chain Based on an Achiral Cu(II) Complex”, Chihiro Kachi-Terajima,* Megumi Ishii, Toshiaki Saito, Chikahide Kanadani, Takunori Harada, and Reiko Kuroda, Inorg. Chem., 2012, 51, 7502–7507.
  13. “Assembled Structures and Magnetic Properties of Viologen–[M(mnt)2] Charge-transfer Salts (mnt = maleonitriledithiolato; M = Cu, Ni, Pt)”, Tomoyuki Mochida,  Yusuke Funasako, Takanori Kishida, Chihiro Kachi-Terajima, Inorg. Chim. Acta., 2012, 384, 111-116.
  14. “Transformation of a CuII Thiazolo-1,2,4-triazine Derivative from a Metastable Coordination Network to a Monomer in Solution and Vapor Conditions”, Akiko Hori, Takahiro Kikuchi, Kumiko Miyamoto, Takashi Okano, Chihiro Kachi-Terajima, Hiroshi Sakaguchi, Eur. J. Inorg. Chem., 2011, 3059-3066.
  15. “Luminescence tuning of imidazole-based lanthanide(III) complexes [Ln = Sm, Eu, Gd, Tb, Dy]”, Chihiro Kachi-Terajima,* Katsuya Yanagi, Toru Kaziki, Takafumi Kitazawa and Miki Hasegawa, Dalton Trans., 2011, 40, 2249 (Themed issue on New Talent: Asia).
  16. “MnIII Salen-type Single-molecule Magnet Fixed in a Two-dimensional Network”, Chihiro Kachi-Terajima,* Erina Mori, Tasuku Eiba, Toshiaki Saito, Chikahide Kanadani, Takafumi Kitazawa, Hitoshi Miyasaka, Chem. Lett., 2010, 39.
  17. “Structural and Magnetic Study of O2 Molecules Arranged along a Channel in a Flexible Single-Crystal Host Family”, S. Takamizawa, E. Nakata, T. Akatsuka, C. Kachi-Terajima, R. Miyake, J. Am. Chem. Soc., 2008, 130 (52), 17882-17892.
  18. “Cubic Metal-Organic Polyhedrons of Nickel(II) Imidazoledicarboxylate Depositing Protons or Alkali Metal Ions”, Q. Xu, R.-Q. Zou, R.-Q. Zhong, C. Kachi-Terajima, S. Takamizawa, Crystal Growth & Design., 2008, 8, 7, 2458–2463.
  19. “Isotope Effect on Spin-crossover Transition in a New Two-dimensional Coordination Polymer [FeII(C5H5N)2][AuI(CN)2]2, [FeII(C5D5N)2][AuI(CN)2]2, and [FeII(C5H515N)2][AuI(CN)2]2” T. Kosone, C. Kachi-Terajima, C. Kanadani, T. Saito, T. Kitazawa, Chem. Lett., 2008, 37, 7, 754-755.
  20. “A Two-step and Hysteretic Spin-crossover Transition in New Cyano-bridged Hetero-metal FeIIAuI 2-Dimensional Assemblage”, T. Kosone, C. Kachi-Terajima, C. Kanadani, T. Saito, T. Kitazawa, Chem. Lett., 2008, 37, 4, 422-423.
  21. “Triply Interpenetrated Structure of {MnII(L)2[AgI(CN)2]2}-{MnII(H2O)2[AgI(CN)2]2} (L = 4-CNpy or py-4-aldoxime)”, T. Kawasaki, C. Kachi-Terajima, T. Saito, T. Kitazawa, Bull. Chem. Soc. Jpn., 2008, 81, 2, 268–273.
  22. “Single-Molecule Magnet Behavior in Heterometallic MII−MnIII2−MII Tetramers (MII = Cu, Ni) Containing MnIII Salen-Type Dinuclear Core”, C. Kachi-Terajima, H. Miyasaka, A. Saitoh, N. Shirakawa, M. Yamashita, R. Clérac, Inorg. Chem., 2007, 46, 5861-5872.
  23. “Alcohol-Vapor Inclusion in Single-Crystal Adsorbents [M2(bza)4(pyz)]n (M=Rh, Cu): Structural Study and Application to Separation Membranes”, S. Takamizawa, C. Kachi-Terajima, M. Kohbara, T. Akatsuka, T. Jin, Chem. Asian. J., 2007, 2, 837-848.
  24. “Structural and Magnetic Study of N2, NO, NO2, and SO2 Adsorbed within a Flexible Single-Crystal Adsorbent of [Rh2(bza)4(pyz)]n”, C. Kachi-Terajima, T. Akatsuka, M. Kohbara, S. Takamizawa, Chem. Asian. J., 2007, 2, 40-50.
  25. “Local Structure and Xenon Adsorption Behavior of Metal-Organic Framework System [M2(O2CPh)4(pyz)]n (M = Rh and Cu) As Studied with Use of Single-Crystal X-ray Diffraction, Adsorption Isotherm, and Xenon-129 NMR”, T. Ueda, K. Kurokawa, T. Eguchi, C. Kachi-Terajima, S. Takamizawa, J. Phys. Chem. C, 2007, 111, 1524-1534.
  26. “Magnetic Properties of Nitric Oxide Adsorbed within Channel Crystals”, C. Kachi-Terajima, T. Akatsuka, M. Kohbara, S. Takamizawa, Polyhedron, 2007, 26, 1876-1880.
  27. “From an ST = 3 Single-Molecule Magnet to Diamagnetic Ground State Depending on the Molecular Packing of MnIII salen-type Dimers Decorated by N,N'-Dicyano-1,4-naphthoquinonediiminate Radicals”, C. Kachi-Terajima, H. Miyasaka, K-i. Sugiura, R. Clérac, H. Nojiri, Inorg. Chem., 2006, 45, 4381-4390.
  28. “Nichel(II) and Iron(II) Mononuclear Complexes with 1-Methylimidazole-2-Aldoximate: New Building Units for Molecule-Assembled Magnetic Materials”, H. Miyasaka, A. Saitoh, S. Yanagida, C. Kachi-Terajima, K-i. Sugiura, M. Yamashita, Inorg. Chim. Acta., 2005, 358, 3525-3535.
  29. “Unprecedented Soliton Formation Mechanism in Quasi-One-Dimensional Chloro-Bridged PtII-PtIV Mixed-Valence Compound, {[Pt(en)2][PtCl2(en)2]}3(CuCl4)4+12H2O”, M. Yamashita, H. Aso, S. Matsunaga, K. Takizawa, K. Nakata, C. Kachi-Terajima, F. Iwahori, T. Ishii, H. Miyasaka, K-i. Sugiura, T. Kawashima, K. Takai, N. Kuroda, M. Shiro, H. Kishida, H. Okamoto, H. Takahashi, H. Tanaka, K. Marumoto, S. Kuroda, Chem. Lett., 2003, 32, 3, 278-279.
  30. “Tuning of Electronic Structures of Quasi-One-Dimensional Bromo-Bridged Ni(III) Complexes with Strong Electron-Correlation by Doping of Co(III) Ions, [Ni1-XCoX(chxn)2Br]Br2”, M. Yamashita, K. Yokoyama, S. Furukawa, T. Manabe, T. Ono, K. Nakata, C. Kachi-Terajima, F. Iwahori, T. Ishii, H. Miyasaka, K-i. Sugiura, H. Matsuzaki, H. Kishida, H. Okamoto, H. Tanaka, Y. Hasegawa, K. Marumoto, H. Ito, S. Kuroda, Inorg. Chem., 2002, 41, 1998-2000.
  31. “Structure and Electrochemistry of the Bridging-Ligand mono-Substituted Diruthenium Compound. [RuII,III(O2CCH3)(admpym)(Cl)(MeOH)] (Hadmpym = 2-amino-4,6-dimethyl-pyrimidine)”, C. Kachi-Terajima, H. Miyasaka, T. Ishii, K-i. Sugiura, M. Yamashita, Inorg. Chim. Acta., 2002, 332, 210-215.
  32. “Tuning of Spin Density Wave Strengths in Quasi-One-Dimensional Mixed-Halogen- Bridged Ni(III) Complexes with Strong-Electron Correlation, [NiIII(chxn)2Cl1-xBrx](NO3)2”, T. Manabe, K. Yokoyama, S. Furukawa, C. Kachi-Terajima, K. Nakata, F. Iwahori, H. Miyasaka, K-i. Sugiura, M. Yamashita, H. Kishida, H. Okamoto, Inorg. Chem., 2002, 41, 4993-4995.
  33. “A New Metal-Metal Bonded Diruthenium(II,III) Compound Bridged by the Dianionic Trident Ligand N-(2-Pyridyl)-2-Oxy-5-Chlorobenzylaminate (5-Clsalpy2-)”, H. Miyasaka, C. Kachi-Terajima, T. Ishii, M. Yamashita, J. Chem. Soc., Dalton Trans., 2001, 1929-1930.
  34. “Syntheses and Physical Properties of Quasi-One-Dimensional Halogen-Bridged CuII-PtIV Mixed-Metal Complexes, [Cu(chxn)2][PtX2(chxn)2]X4”, T. Kawashima, K. Takai, H. Aso, T. Manabe, K. Takizawa, C. Kachi-Terajima, T. Ishii, H. Miyasaka, H. Matsuzaka, M. Yamashita, H. Okamoto, H. Kitagawa, M. Shiro, K. Toriumi, Inorg. Chem., 2001, 40, 6651-6655.
  35. δMM*-πL Odd Electron Delocalization onto Aromatic Bridging Ligands in a Paramagnetic Dirhodium Complex and Intermolecular π-Stack Interaction in Crystal”, T. Kawamura, H. Kachi, H. Fujii, C. Kachi-Terajima, Y. Kawamura, N. Kanematsu, M. Ebihara, K. Sugimoto, T. Kuroda-Sowa, M. Munakata, Bull. Chem. Soc. Jpn., 2000, 73, 657-668.
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